I've been playing with Lucio's excellent "embossed snow" (
http://forums.planetside.co.uk/index.php?topic=753.0) and came across an interesting edge case: when the Lambert shader is switched on (as described in p.6 of that thread), and the Sun is on the horizon, you get this rather strange yellow glow along the edge of the snow, which I doubt is what would happen in real life.
And for an even weirder effect, this time in the sky, try plugging a Lambert shader in between the Atmosphere and a cloud layer (in this case a very high cirrus):
May appeal to those who want to make sci-fi type scenes.