Hi Glenn,
You need to go to the shader for the leaf texture. Uncheck "Unpremultiply colour" in the Images tab and add the leaf texture image to the "Opacity image" param in the Opacity tab. Precise details of how to achieve this are left as an exercise :-), but let me know if you get stuck.
I should add it's the "Unpremultiply colour" setting which is causing the colour to blow out. You need to add the leaf texture image to the "Opacity image" param to make the leaves transparent in the right places.
Regards,
Jo