If you got 6 gigs of ram, you should not be running any 32bit os's as you automatically loose 2+ gigs ram there.
And yes, in 64bit you automatically will benefit to a up to a theoretical limit of 4gb limit for a 32 bit program (assuming the resources arnt being used by another program, etc etc). Also you will have access to all 6gb in 64bit. And with 64bit, once terragen builds a 64bit version, you will be able to utilize all 6gb (except whats being used by the os/other applications).