I might be wrong, but it might be the "Rayleigh Scattering" effect.
Try it out on a completely flat ground (like in your HDRI) and check out. Perhaps it is visible by default?
If not, the fastest (though uninventive) way to achieve such an effect is to... add another sunlight opposite the mian light source. A 0.5 - 1.25 powered, white sunlight, lowered just below the horizon. If you opt for this solution however, keep in mind that you'll need to tweak atmosphere as well to avoid colour decays.