Thanks guys! I agree with the both of you. I'd thought about adding a little DOF after a few test renders and put it off to just get a decent render. The DOF settings are probably intuitive to most people, it eludes me and I usually have to spend a lot of time fiddling. Is their a trick? I.m going to see if I get lucky and get results quickly with it today, sometimes this happens.
The graininess on the rock was a failed attempt to add some subtle texture. Turns out it wasn't so subtle.

I had tried a series of failed attempts to mask to rises crevices etc. and I was unsuccessful. I will attach, maybe I have the nodes setup incorrectly. In the meantime I think will just remove it and give Daniil's erosion a go and see if I can get some interesting results that way.
I appreciate the feedback gentlemen.