That'll be mostly in the 'atmosphere' node settings.
You can raise the red sky decay, cloud GI colour, or even cloud colour itself, if you want natural cloud, though, leave the cloud colour a shade of grey, the atmo will do the work for you. I have an almost identical cloud to this(although, Frank will always rule the skies around here,

)...
http://forums.planetside.co.uk/index.php?topic=4833.0It's the atmosphere that provides the overpowering colour. And a low, strong sun, obviously.
You can boost the glow sliders well past their maximum by just keying in a number, aswell. I think I did this here, too.